Abstract
Metathesis reactions of dinuclear halo-bridged complexes of the late transition metals have been studied by NMR. For selected combinations of 15 different complexes, it has been shown that asymmetric complexes are formed in a dynamic equilibrium. The equilibrium constants have been calculated and the trends therein are discussed. A theoretical analysis of halo-bridged complexes containing (C3H5)MX, (H3P)MX2, [(H3P)2MX]+, and (ppy)2RhCl fragments (M = Pd, Pt; X = Cl, Br, I; ppy = anion of 2-phenylpyridine) has been carried out to gain further insight into (i) the influence of the bridging halogen atoms on the equilibrium, (ii) the electron transfer, (iii) the thermodynamic stability and the dynamic equilibrium behaviour, and (iv) structural differences between symmetric and asymmetric halo-bridged complexes.
Submitted Version (
Free)
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
