Abstract
The construction of triplet-triplet annihilation upconversion (TTA-UC) systems with upconversion (UC) emission efficiency at low power densities is still under continuing exploration. From an environmental point of view, the utilization of purely organic pairs is more beneficial than the involvement of transition-metal complexes. In this context, 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes, which can be found in a wide range of applications, have been previously used as suitable sensitizers in TTA-UC systems. The versatility of these scaffolds makes them magnificent objectives for designing and synthesizing potential entities with different target abilities. Herein, we prepared several asymmetric BODIPY dyes with excellent optical properties to be applied to a bimolecular TTA-UC system. In the presence of 2,5,8,11-tetra-tert-butylperylene (TBPe) as a suitable annihilator, a green-to-blue light conversion was clearly observed by means of detailed spectroscopic investigations. The results revealed a high UC emission efficiency (ηUC) of ∼8%, together with a low threshold intensity (I th) of ∼40-50 mW/cm2. All data indicated that these asymmetric BODIPY dyes were ideal sensitizers for TTA-UC, providing a particular design for further investigations.
Published Version
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