Abstract
The authors report an asymmetric allylic substitution of allyl phosphates with aryl- and alkenylboronic acid esters. This reaction is catalyzed by a copper/N-heterocyclic carbene complex which gives access to tertiary and quaternary stereocenters with high regio- and enantioselectivity. The protocol has also been extended to γ,γ-disubstituted allyl phosphate substrates.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
