Abstract
Anomalous association constants have been obtained from the kinetics of the decay of substituted p-benzoquinone–hexamethylbenzene systems. The apparent association constants for several systems have been shown to be dependent on the concentration of the component in excess. It is suggested that these observations are the result of the formation of termolecular complexes as well as of the anticipated 1:1 complexes. Association constants for the double equilibria have been evaluated in several cases.
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Schedule a callMore From: Journal of the Chemical Society B: Physical Organic
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