Abstract

Abstract The relations between the associated complex formation and the concentration fluctuation in a binary solution were derived. The concentration fluctuation of a chloroform–diethyl ether system was determined by observing light-scattering spectra at various concentrations. The theoretical values of the concentration fluctuation of this system were calculated from the proposed relation by the use of the shape and the number population of the associated complex, as determined from the infrared absorption intensity measurements. The observed and calculated concentration fluctuations agreed quite well.

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