Abstract

Dilute acid pretreatment of lignocellulosic biomass at higher temperatures (>160 °C) solubilizes/removes hemicelluloses (xylan, arabinan, mannan, galactan) and acid-soluble lignin (ASL), but, it does not remove acid-insoluble lignin (AIL). During acid pretreatment, the condensation and redeposition of coalesced lignin over cellulose fibers reduces the access of cellulose to cellulases. For higher delignification, various multistage pretreatments are available, however, all these are energy/chemical intensive methods. Therefore, an effective pretreatment which provides increased cellulose accessibility by enhanced removal of hemicelluloses and lignin in a single-step would be preferred. Our investigation reports a novel assisted single-step acid pretreatment (ASAP) process for enhanced delignification of biomass under acidic conditions. Pretreatment of rice straw (particle size of 20 mm) with H2SO4 (0.75% v/v) + boric acid (1% w/v) + glycerol (0.5% v/v) (solid/liquid (S/L), 1:5) at 150 °C for 20 min remove...

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