Abstract
Ruthenium–BINAP catalysts are commonly used in asymmetric hydrogenations and provides high enantioselectivity over a wide range of substrates. Herein we focus on a single Ru(II)–BINAP catalyst prepared from cyclooctadienyl ruthenium dichloride and ( R)-BINAP in the presence of triethylamine and report on the structure identified using NMR as the diethylammonium salt [(C 2H 5) 2NH 2] +[Ru 2Cl 5((R)-BINAP) 2] −.
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