Abstract
The photoelectron spectrum of HCl up to 32 eV is analyzed with ab initio MO Cl calculations. The potential energy curves of most of the highly excited states of the ion HCl + are correctly drawn to near the dissociation limit, and the Franck-Condon factors (FCF) from the neutral ground state are evaluated. By comparing the experimental spectrum with the theoretical FCF distribution, six observed bands between 20 and 32 eV are assigned. One of them turns out to be a Rydberg state converged to the ground state of HCl 2+.
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