Abstract
A novel assignment of the η(CoC) and δ(CoCO) modes of the compounds ClHgCo(CO) 4, Hg{Co(CO) 4} 2, Co 2(CO) 8 and their axially substituted derivatives is presented. This assignment is based on a comparison of the frequency shifts due to substitution with the shifts observed in the spectra of the corresponding iron carbonyl compounds. The η(FeC) and δ(FeCO) vibrations are assigned unambiguously.
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