Assessment on biodegradability prediction of tannery wastewater using EPI Suite BIOWIN model.

Abstract

Biodegradation of organic compounds would reveal important information on the final fate of a chemical in the environment. However, establishing biodegradability and fate of a chemical is cumbersome. In this scenario, the use of multimedia models help in predicting the fate and half-life of any compound to establish biodegradability. The study commenced with collection of wastewater samples, after primary and secondary treatment, from a Common Effluent Treatment Plant (CETP) treating tannery wastewater. The samples were subjected to gas chromatography-mass spectrometry (GC-MS) analysis. The GC-MS analysis identified that polyphenolic compounds were detected after biological treatment. The identified compounds emanated from tanning, dyeing, and fatliquoring process of leather making. Estimation Program Interface (EPI) Suite BIOWIN 3 and BIOWIN 4 model prediction revealed that while the primary biodegradation time-frame ranged from days to weeks, the ultimate biodegradation took weeks in the case of all the detected compounds. This study established that BIOWIN model could be used as a screening tool to determine biodegradability of complex chemicals used in tanneries and help to design better treatment facility with enhanced efficiency for removal of polyphenolic compounds. This methodology can also be applied to other industrial wastewaters containing recalcitrant chemicals, and with the help of BIOWIN model, information on biodegradability of chemicals present in the wastewater can be obtained.