Abstract
The rivers of agricultural catchment areas are particularly vulnerable to eutrophication, which causes nitrate nitrogen (N-NO3) that can be easily leached from the cropland. In 1991, the EU implemented the Nitrates Directive (ND) to identify and reduce the negative effects of nitrates in water. According to this regulation, in 2018, the whole territory of Poland was classified as Nitrate Vulnerable Zone (NVZ). The aim of the study was to assess the validity of the introduction of NVZs in large areas of the river catchment level. Statistical data on agricultural changes for individual provinces of Poland and for the whole country were analyzed. A one-way analysis of variance (ANOVA) was used to assess the N-NO3 content in the water at different locations along the river within four rivers in the Odra basin. The results indicated that higher concentrations are observed in the upper part of the studied catchments, which reached a maximum of 25.0 mg N-NO3·dm−3. However, average values rarely exceeded 11.3 mg N-NO3·dm−3, the limit according to the Nitrates Directive. The large variability in N-NO3 content suggests the need to redefine the actual NVZs since it is essential for the appropriate implementation of programs aimed at restoring water quality according to ND.
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