Abstract

Biomethane, as a replacement for natural gas, reduces the use of fossil-based sources and supports the intended change from fossil to bio-based industry. The study assessed different biomethane utilization routes for production of methanol, dimethyl ether (DME), and ammonia, as fuel or platform chemicals and combined heat and power (CHP). Energy efficiency and environmental impacts of the different pathways was studied in a life cycle perspective covering the technical system from biomass production to the end product. Among the routes studied, CHP had the highest energy balance and least environmental impact. DME and methanol performed competently in energy balance and environmental impacts in comparison with the ammonia route. DME had the highest total energy output, as fuel, heat, and steam, among the different routes studied. Substituting the bio-based routes for fossil-based alternatives would give a considerable reduction in environmental impacts such as global warming potential and acidification potential for all routes studied, especially CHP, DME, and methanol. Eutrophication potential was mainly a result of biomass and biomethane production, with marginal differences between the different routes.

Highlights

  • Biogas [composed mainly of methane (CH4) and carbon dioxide (CO2)] produced from waste, residues, and energy crops through anaerobic digestion (AD) is a versatile renewable energy source that can be used for replacement of fossil fuels in combined heat and power (CHP) production or as a vehicle fuel after upgrading

  • Comparison of the different bio-based routes assessed in this study with an input-based functional unit (FU) (1 ha of maize cultivation per year) revealed that the base CHP route had the best performance regarding energy balance and environmental impact categories

  • primary energy (PE) input and environmental impacts from CHP production were closely related to the biomass-to-biomethane unit, with a low contribution from the CHP unit itself

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Summary

Introduction

Biogas [composed mainly of methane (CH4) and carbon dioxide (CO2)] produced from waste, residues, and energy crops through anaerobic digestion (AD) is a versatile renewable energy source that can be used for replacement of fossil fuels in combined heat and power (CHP) production or as a vehicle fuel after upgrading (removal of carbon dioxide). Upgraded biogas (biomethane) can be injected to the gas grid, replacing natural gas as a feedstock for producing chemicals and materials (Weiland, 2010). The production of biogas through AD has been rated as an energy-efficient and environmentally beneficial technology for renewable energy production (Fehrenbach et al, 2008). The limited production rate and methane yield of these feedstocks has led to the introduction of energy-rich co-feedstocks in order to increase biogas production. The cultivation of these crops produces the lowest specific GHG

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