Abstract

A quite simple method is proposed for the assessment of extremely cold subarctic climate environment destruction of the basalt fiber reinforced epoxy (BFRE) rebar. The method involves the comparison of experimentally obtained long-term moisture uptake kinetic curves of unexposed and exposed BFRP rebars. A moisture uptake test was carried out at the temperature of 60 °C and relative humidity of 98 ± 2% for 306 days. The plasticization can be neglected because of low-level moisture saturation (<0.41% wt.); the swelling and structural relaxation of the polymer network can be neglected due to the high fiber content of BFRP rebar; moisture diffusion into the basalt fibers can be neglected since it is a much lesser amount than in the epoxy binder. These assumptions made it possible to build a three-stage diffusion model. It is observed that an increase in the density of defects with an increase in the diameter of the BFRP rebar is the result of the technology of manufacturing a periodic profile. The diffusion coefficient of the BFRP rebar with a 6, 10, or 18 mm diameter increased at an average of 82.7%, 56.7%, and 30%, respectively, after exposure to the climate of Yakutsk during 28 months, whereas it was known that the strength indicators had been increased.

Highlights

  • The subject of the study is inextricably linked with the actual problem of ensuring high resistance of the strength properties of polymer composites to aggressive environments [1,2,3,4,5,6,7,8,9,10], including the forceful impacts of subarctic climate on the composites [10,11,12]

  • In [12], it is shown that the indicators’ strength of basalt fiber reinforced polymer (BFRP) rebar, which has been under the influence of destructive processes of extremely cold subarctic climate for several years, has improved

  • Moisture uptake kinetics were calculated as the percent change in mass (1)

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Summary

Introduction

The subject of the study is inextricably linked with the actual problem of ensuring high resistance of the strength properties of polymer composites to aggressive environments [1,2,3,4,5,6,7,8,9,10], including the forceful impacts of subarctic climate on the composites [10,11,12]. Usually the initial free volume content is unknown; polymer composite materials (PCM) can contain defects and capillaries in the interface fiber/binder, depending on the initial composition, reinforcement design, manufacturing technology, and environmental conditions. This type of free volume can be the generating part of the moisture content of the PCM [18,19,20,21]. For an adequate quantitative evaluation of the free volume in unidirectional PCM, it is necessary that the samples with different heights were exposed to moisture for a long time

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