Abstract

In recent years, superhydrophilic and photocatalytic self-cleaning nanocoatings have been widely used in the easy-to-clean surfaces field. In the building sector, self-cleaning glass was one of the first nanocoating applications. These products are based on the photocatalytic property of a thin layer of titanium dioxide (TiO2) nanoparticles deposited on the surface of any kind of common glass. When exposed to UV radiation, TiO2 nanoparticles react with the oxygen and water molecules adsorbed on their surface to produce radicals leading to oxidative species. These species are able to reduce or even eliminate airborne pollutants and organic substances deposited on the material’s surface. To date, TiO2 nanoparticles’ benefits have been substantiated; however, their ecological and human health risks are still under analysis. The present work studies the ecodesign of the industrial scale-up of TiO2 nanoparticles self-cleaning coated float glass production performed by the life cycle assessment (LCA) methodology and applies new human toxicity indicators to the impact assessment stage. Production, particularly the TiO2 nanoparticle application, is the life cycle phase most contributing to the total damage. According to the ecodesign approach, the production choices carried out have exacerbated environmental burdens.

Highlights

  • Since Fujishima and Honda discovered the photo-splitting of water in a titanium dioxide (TiO2 )anode photochemical cell in 1972 [1], research in the self-cleaning field based in photocatalytic nanoparticles has continuously grown

  • Anode photochemical cell in 1972 [1], research in the self-cleaning field based in photocatalytic nanoparticles has continuously grown

  • life cycle assessment (LCA) analysis of a production process at a laboratory scale should not be considered since the LCA results do not necessarily represent the environmental burdens which would be caused after scaling up to typical mass production [36,37,38,39]

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Summary

Introduction

Anode photochemical cell in 1972 [1], research in the self-cleaning field based in photocatalytic nanoparticles has continuously grown. If the e− -h+ pair interacts with adsorbed species, it forms radicals capable of oxidizing a wide range of organic pollutants into H2 O and CO2 [3]. This property of TiO2 can be used to impart the self-cleaning functionality to a variety of materials including tiles, glass, plastic coatings, panels, wallpapers, window blinds, paints, tunnel walls and road blocks to name a few [4,5,6]—and the field is still growing.

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