Abstract

Protective coatings offer one route to increase the lives of heat exchangers in pulverised fuel power plants. A range of candidate coatings have been exposed on the waterwall and superheaters of a 500 MWe UK power station unit for periods of up to ~4 years (24,880 operating hours), during which time this unit was fired on a mixture of UK and world-traded coals. Both nickel- and iron-based candidate coatings were included, applied using high velocity oxy-fuel or arc-wire process; a selection of these also had a surface sealant applied to investigate its effectiveness. Dimensional metrology was used to evaluate coating performances, with SEM/EDX examinations used to investigate the various degradation mechanisms found. Both the waterwall and superheater environments generated their characteristic corrosion damage morphologies which depended on the radial positions around the tube. Coating performances were found to depend on the initial coating quality rather than composition, and were not improved by the use of a sealant.

Highlights

  • Pulverised coal-fired power stations currently produce much of the electricity used in the world, but they generate CO2 emissions and often have efficiencies of only *35 to 40% [1]

  • This paper reports the results of the long-term exposure of a selection of candidate protective coatings on the waterwalls and superheater tubes within a 500 MWe pulverised fuel-fired unit of a UK power station

  • Coatings Exposed on Waterwall Tubes The cross-sections through the exposed samples showed that all of the coatings had experienced fireside corrosion on their surfaces at the crown (i.e. 12 o’clock positions), but only the highvelocity oxy-fuel (HVOF) alloy 625 coatings had disappeared completely

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Summary

Introduction

Pulverised coal-fired power stations currently produce much of the electricity used in the world, but they generate CO2 emissions and often have efficiencies of only *35 to 40% [1]. This paper reports the results of the long-term exposure of a selection of candidate protective coatings on the waterwalls and superheater tubes within a 500 MWe pulverised fuel-fired unit of a UK power station. These coatings were manufactured and installed during a plant outage in 2011, as part of the UK ASPIRE R&D project. The coatings were exposed for 24,880 operating hours before being removed and examined during the unit’s major outage in 2015, as part of the EU NEXTGENPOWER R&D project During this exposure, the power plant was fired using a mixture of UK and world-traded coals. There were significant differences between the performances of coatings in the waterwall and superheater environments

Experimental Procedures
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