Assessing the uranium DGT-available fraction in model solutions

Abstract

The uranium speciation in humic acid (HA) and fulvic acid (FA) model solutions was investigated by diffusive gradients in thin films (DGT). A reference solution was used to normalize the DGT data from different samples. This approach was used to assess uranium DGT-available fraction (FU), which was calculated from experimental data and reflect both the mobility and lability of uranium species. FU decreased with increasing HA or FA concentrations, because more uranium was able to bind the strong binding sites of HA or FA. When copper was spiked, FU increased due to the competition between copper and uranium. In HA model solutions, an increase of ionic strength could increase FU, and when pH was greater than 7, FU increased significantly. The DGT uptake factor (φ), which can be obtained from data fitting, is the ratio of the product of diffusion coefficient and lability degree of the unknown sample to that of the reference solution. In U-HA-NaHCO3 solutions, UO2(CO3)22− had a relatively high φ value and might be the most DGT-available species. This approach allows the comparison of DGT data from different samples, and combining with a data fitting procedure, it can be used to investigate the distribution of metal species.