Assessing the performance of coral reef-like floc towards the removal of low molecular weight organic contaminant

Abstract

The removal of low molecular weight (MW) organics by coagulation is always a challenge in water treatment. In this study, we proposed a novel coagulation strategy: continuous dosing coagulation (CDC). The metallic coagulant and alkali were continuously dosed into water that was pre-acidized, rather than adding all the coagulant and alkali at once as in conventional coagulation (CC). The CDC process promoted the removal of different low MW organics, performing 15% better than the CC process. The best performance occurred at initial pH 6 and the coagulant dosing rate was 2 mg/(L·min). Under optimal conditions, the continuously dosed coagulant formed medium polymer Al in the early stages, which bound low MW organics to form complexes. Then, the subsequently dosed coagulant could adhere to the primary complexes and form coral reef-like surfaces with higher zeta potential and specific surface area. Each freshly formed surface bound contaminants and covered the previous surface. As a result, more dissolved low MW organic contaminants were included in the interior of flocs. However, in the CC process, all the coagulant was dosed at once, resulting in the rapid formation of aluminum hydroxide clusters, which had cotton-like surfaces with fewer binding sites. To achieve similar organic removal in treating secondary effluent, the CDC dosage was half of the CC dosage, indicating the potential economic benefits. The CDC process is a promising technology and the application in various water treatments should be further investigated.