Abstract

Understanding a material’s fire behaviour implies to know the thermal decomposition processes. Thermal analysis techniques are widely employed to study thermal decomposition processes, especially to calculate the kinetic and thermal properties. Cardboard boxes are widely employed as rack-storage commodities in industrial buildings. Hence, the characterization of the cardboard is considered a key factor for fire safety engineering, because it enables the determination of its thermal behaviour at high temperatures. The employment of mathematical or computational models for modelling the thermal decomposition processes is commonly used in fire safety engineering (FSE). The fire dynamics simulator (FDS) software is one of the most commonly used computational fluid dynamics softwares in FSE to address thermal analysis. To properly set up FDS and obtain accurate results, the numerical values of the thermal and kinetic properties are needed as input data. Owing to the large number of variables to be determined, a preliminary study is bound to be helpful, which can well assess the influence of each variable over the pyrolysis model, discarding or restricting their influence. This study, based on the Monte Carlo method, presents a sensitivity analysis for the variables utilized as input data by the FDS software. The results show the conversion factor α, i.e. the mass involved in each reaction, and the triplet kinetics have a major impact on the reproduction of the thermal decomposition process in fire computer modelling.

Highlights

  • To understand the fire behaviour of materials, it is necessary to know their decomposition processes

  • The results achieved by shuffle complex evolution (SCE) in combination with the fire dynamics simulator (FDS) pyrolysis model confirm the usefulness of the methodology and reaction scheme utilized in this study, as proved previously [6, 20, 45]

  • This study aims to analyse the role of the variables of the FDS software that allow the user to model cardboard thermal decomposition processes

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Summary

Introduction

To understand the fire behaviour of materials, it is necessary to know their decomposition processes. In a simultaneous thermal analysis (STA) test, which integrates TG and DSC experiments, the samples have the milligram scale to avoid the thermal diffusion occurring inside them and the influence of specific heat or conductivity. While the effects of different initial sample masses were analysed in [4], Comesaña et al [5] studied the evolution of internal heating of the sample and thermal lag during an STA test. Despite the small size of the samples, variables such as conductivity (k), specific heat (Cp), emissivity (ε), and absorption coefficient (η) determined the internal heating of the sample

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