Assesment of the risk of degazation of the Black Sea: type of limnological disaster on lake Nyos reconsidered

Abstract

The possibility of a repetition of the limnological catastrophe in the Black Sea is considered. It is shown that, in contrast to the volcanic lakes of Africa Nyos and Manun, where limnological catastrophes occurred in the 1980s, the concentration of dissolved gases in deep waters is significantly less than the saturation value. This eliminates the mechanism of so called “eruption” of carbon dioxide such as gas lift. However, on a smaller scale, significant methane releases are possible during strong eruptions of underwater mud volcanoes. The mechanism for the release of carbon dioxide from the lake into the atmosphere is so similar to a volcanic eruption that mathematical models developed for ordinary volcanoes are used to describe it. In both cases, the rise of erupted masses occurs due to an increase in the buoyancy of the gas-liquid mixture, which carries with it particles of the environment. The formation and growth of gas bubbles at intermediate depths occurs provided that the total partial pressure of all gases inside the bubble exceeds the hydrostatic pressure at a given depth. The article shows that the concentration of dissolved methane in the Black Sea is much less than the saturation level. Due to the relatively low solubility of methane in water, methane bubbles are able to overcome a significant depth range. And as additional components of the gas mixture, together with methane, carbon dioxide and hydrogen sulfide can thus enter the atmosphere. It was concluded that as the water temperature in the Black Sea increases due to climate change, the reserves of methane gas hydrate at the bottom of the sea will begin to decompose, which will also be accompanied by jet gas release. At the same time, methane can escape to the surface from depths of no more than 900 m.