Abstract
Chiral capsules with polar interiors (reversed capsules) undergo heterochiral sorting and exhibit positive mutalism - both hemispheres mutually benefit from the association. This feature can be coupled with partial reversibility of the formation reaction and utilized to amplify synthesis of hybrid capsules made of hemispheres that cannot be formed independently.
Highlights
Chiral capsules with polar interiors undergo heterochiral sorting and exhibit positive mutalism – both hemispheres mutually benefit from the association
This feature can be coupled with partial reversibility of the formation reaction and utilized to amplify synthesis of hybrid capsules made of hemispheres that cannot be formed independently
In the current communication we show that the stability gained from non-covalent assembly of capsular dimers can be used to control their own chemical synthesis
Summary
Chiral capsules with polar interiors (reversed capsules) undergo heterochiral sorting and exhibit positive mutalism – both hemispheres mutually benefit from the association. This feature can be coupled with partial reversibility of the formation reaction and utilized to amplify synthesis of hybrid capsules made of hemispheres that cannot be formed independently. In this way the most stable assemblies have a chance to be amplified.[3,4,5,6] In the current communication we show that the stability gained from non-covalent assembly of capsular dimers can be used to control their own chemical synthesis.
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