Abstract
An unusual supramolecular coordination polymer [{Ag(bpy)}2(Hbpy)][PW12O40] (1) has been synthesized under hydrothermal conditions and structurally characterized by elemental analysis, IR, TG, PXRD, XPS, UV–vis, and single-crystal X-ray diffraction. In compound 1, Keggin-type [PW12O40]3− clusters as templates induce the supramolecular [{Ag(bpy)}2(Hbpy)]3+ layer to 3D hexagonal metal–organic framework (MOF), which represents two-fold interpenetrating MOF with 1-D helical channels constructed from alternate left- and right-handed chains. In addition, compound 1 exhibits good electrocatalytic activity on the reduction of nitrite and fluorescent properties in the solid state at room temperature.
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