Abstract
AbstractThe incorporation of F atoms endows a diethenylbiphenyl‐based electron donor with configurational stability and SNAr reactivity. The former enables the dynamic redox pair of (Rax)‐1/(Rax,R,R)‐12+ to exhibit drastic UV/Vis and CD spectral changes upon electrolysis, whereas the latter makes it possible for (Rax)‐1 to serve as a useful chiral synthon for the production of larger assemblies [(Rax,Rax)‐2 d,p,m and (Rax,Rax,Rax)‐3] containing two or three dyrex units. These dyads and triad also exhibit a clean electrochiroptical response with isosbestic points owing to one‐wave multi‐electron transfer.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
