Abstract
The polymeric silver(I)–thiolate complex [{Ag8(µ4-SC2H4- NH3)6Cl6}Cl2]n has been prepared from the assembling reaction of silver chloride and 2-mercaptoethylamine hydrochloride in DMF; X-ray diffraction analysis shows the complex has a one dimensional chain structure and all the sulfur atoms of the thiolates exhibit µ4 bonding bridging four silver(I) centers.
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