Abstract
The reactions of K3[Cu(CN)4], Me3SnCl and methylpyrazine (Me-pyz) or tetramethylpyrazine (Me4-pyz) in water/dioxane system afforded two new coordination polymers (CP); [{Cu(μ-CN)}2(μ-Me4-pyz)·dioxane] n , 1, and [Cu{μ-Mepyz}{μ-CNSn(Me3)NC–}], 2. X-ray single crystal analysis shows that 1 contains two crystallographically different copper(I) ions which acquire trigonal planar geometry. The structure of 1 contains non-linear (CuCN)∞ chains that are interconnected by the Me4-pyz ligands forming 3D-network structure. The structure of 1 has two-fold interpenetrating 3D-networks with dioxane molecules encapsulated in the voids of the structure. The structures of these CP were also investigated by FTIR and mass spectroscopy, thermal analysis and compared with the prototype compounds. Spectroscopic analyses of 2 confirm the presence of all components (Me3Sn+, Cu(CN)2 − and Me-pyz) and support the composition predicted by elemental analysis. 1 and 2 display strong fluorescence in the solid state at room temperature.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Inorganic and Organometallic Polymers and Materials
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
