Abstract
Topology has long been considered as an abstract mathematical discipline with little connection to material science. Here we demonstrate that control over spatial and temporal positioning of topological defects allows for the design and assembly of three-dimensional nematic colloidal crystals, giving some unexpected material properties, such as giant electrostriction and collective electro-rotation. Using laser tweezers, we have assembled three-dimensional colloidal crystals made up of 4 μm microspheres in a bulk nematic liquid crystal, implementing a step-by-step protocol, dictated by the orientation of point defects. The three-dimensional colloidal crystals have tetragonal symmetry with antiparallel topological dipoles and exhibit giant electrostriction, shrinking by 25-30% at 0.37 V μm(-1). An external electric field induces a reversible and controllable electro-rotation of the crystal as a whole, with the angle of rotation being ~30° at 0.14 V μm(-1), when using liquid crystal with negative dielectric anisotropy. This demonstrates a new class of electrically highly responsive soft materials.
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