Abstract

Reaction of (NBu3H)3[W(CN)8]·H2O and linear trinuclear complexes [Cu(II)2L2Ln(III)(NO3)3] (L = 2,6-di(acetoacetyl)pyridine, Ln = Eu (1), Gd (2), Tb (3) and Dy (4)) leads to the formation of four one-dimensional (1D) complexes. Single crystal X-ray analysis reveals that [W(CN)8](3-) bridges between the [Cu(II)2L2Ln(III)] sub-building units to construct the alternative chains. Magnetic investigation indicates that ferromagnetic interaction occurred between all paramagnetic ions and the slow magnetic relaxation properties were observed in complexes 3 and 4.

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