Asphaltene Gradients and Connectivity Analysis in Reservoirs, Asphaltene Onset Pressure, Bitumen and Tar Mats All Treated Within a Simple, Unified Chemistry Treatment

Abstract

Abstract Asphaltenes can be dispersed in crude oils in 3 different forms; molecules, nanoaggregates (of molecules) or clusters (of nanoaggregates); these forms are codified in the Yen-Mullins model and relate to the extent of solvency of the asphaltenes in the crude oil. Many reservoir studies are used here to show the systematic behavior of the specific asphaltene species in crude oil and the corresponding magnitude of the asphaltene (and viscosity) gradients. In addition, the specific asphaltene species is related to the chemical origin controlling asphaltene onset pressure (AOP) and tar formation and depends on 1) the quality of the live crude oil solvent for asphaltenes and 2) the concentration of asphaltenes. Elevated quantities of solution gas of a reservoir crude oil significantly reduce the solvency of asphaltenes in crude oil. For low concentrations and/or good solvency, asphaltenes are dispersed in crude oils as molecules with small gradients (unless there are large GOR gradients). For moderate concentrations and/or moderate solubility, asphaltenes are dispersed as nanoaggregates with intermediate (gravity) gradients of asphaltenes. With large concentrations and/or poor solvency, asphaltenes are dispersed as clusters with very large gradients in reservoirs. These crude oils can also exhibit higher asphaltene onset pressures and/or phase separated bitumen or tar in the reservoir depending on the origin of asphaltene cluster formation. Secondary gas charge into oil reservoirs can yield tar and/or a high AOP. The effect of biodegradation on these factors is also discussed. The systematics presented here are helpful in understanding a variety of reservoir concerns associated with asphaltenes.