Abstract
1. New cationic o-tolyl and o-fluorophenyl complexes of Ni containing Ph3P, MeCN, or THF ligands have been synthesized. 2. Reaction of these compounds with potassium carboxylates gave the novel o-tolyl and o-fluorophenylbis(triphenylphosphinyl)nickel carboxylates. 3. According to19F NMR data o-tolylbis(triphenylphosphinyl)nickel p-fluorobetizoate contained a highly polarized Ni-O bond.
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