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Abstract
1. Phenyl aryl sulfides were obtained by the arylation of diphenyl disulfide using aryl radicals generated by two methods: 1) by the decomposition of aryldiazonium chlorides in the presence of CuCl2, and 2) by the thermolysis of phenylazotriphenylmethane. 2. The arylation of diphenyl disulfide using aryldiazonium chlorides in the presence of CuCl2 and phenylazotriphenylmethane has a great similarity, which makes it possible to propose that their mechanism is close.
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