Aryl−Perfluoroaryl Substituted Tetracene: Induction of Face-to-Face π−π Stacking and Enhancement of Charge Carrier Properties

Toshihiro Okamoto,Katsumasa Nakahara,Shu Seki,Yutaka Matsuo,Joon Hak Oh,Akinori Saeki,Hylke B. Akkerman,Zhenan Bao

doi:10.1021/cm200356y

Aryl−Perfluoroaryl Substituted Tetracene: Induction of Face-to-Face π−π Stacking and Enhancement of Charge Carrier Properties

Toshihiro Okamoto, Katsumasa Nakahara + Show 6 more

https://doi.org/10.1021/cm200356y

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Journal: Chemistry of materials : a publication of the American Chemical Society	Publication Date: Mar 11, 2011
Citations: 133

Affiliation: The University of Tokyo, Osaka University, Stanford University

#Photoconductivity Measurements #Structure Of Core + Show 8 more

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Abstract

5-Perfluorophenyl-11-phenyltetracene (FPPT) having both aryl (Ar) and perfluoroaryl (FAr) groups has been designed and synthesized to obtain well-defined π−π stacking structure of the tetracene core. Single-crystal X-ray analyses as well as photoconductivity and hole mobility measurements revealed that this strategy is promising for enhancement of the charge carrier properties.

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