Artificial Black Opal Fabricated from Nanoporous Carbon Spheres

Abstract

A nanocasting method via chemical vapor deposition of acetonitrile was successfully employed to fabricate porous carbon colloidal crystal using colloidal crystal from monodispersed mesoporous silica spheres (MMSS) as a sacrificial scaffold. The mesostructure as well as periodic arrays within (111) plane of MMSS were replicated for the carbon colloidal crystal (black opal) with the length scale in the centimeter range. Brilliant iridescent colors were clearly observed for the first time on the black carbon colloidal crystal fabricated from porous carbon spheres, and they changed dramatically in accordance with the observation angle, like natural black opals. Reflection spectra measurements based on 2D surface diffraction and Bragg diffraction in the mirror mode were conducted for the fabricated carbon periodic arrays. The periodicity in the (111) plane as well as in the direction perpendicular to the (111) plane of the colloidal crystal was evaluated by comparing the results obtained from these two measurements. It was found that the periodicity in the direction perpendicular to the (111) surface is not high for the obtained black carbon opal. On the other hand, the relationship between the incident angles and the peak wavelengths of the reflection spectra, collected in the condition where the incident light and the reflected light pass through in the same direction, is governed by an approximation based on 2D surface diffraction. The results imply that the origin of the iridescent colors on the fabricated black carbon opal is derived from the periodicity not in the direction perpendicular to the (111) plane but within the (111) plane.