Abstract
AbstractPurple arsenomethane crystallises in the orthorhombic system, space group Ima2 (C) with a = 5.81, b = 5.79, c = 13.64 Å and 8 units of CH3As in the cell. The structure is polymeric, the arsenic atoms lying on infinite coplanar ladders parallel to a. The distance between two arsenic atoms on one rung of the ladder is 2.4 Å, the distance between two arsenic atoms on the same upright and adjacent rungs is 2.9 Å, and the shortest distance between two arsenic atoms in neighbouring ladders is 3.4 Å. Each arsenic atom is bonded to one methyl group (1.97 Å), and along the ladder upright or on any one rung these methyl groups lie on alternate sides of the ladder.
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