Abstract
The reactions of a number of saturated aliphatic halogen compounds have been studied with arsenic trifluoride using various catalysts. The fluorination can be done in laboratory glassware with a minimum of etching. The advantages of AsF 3 are its liquid state and its ready miscibility with many organic liquids, allowing a wide range of reaction conditions. At atmospheric pressure one or two fluorine atoms could be introduced selectively into a CCl 3 group of polyhaloalkanes. Reaction of mono- and dichloroalkanes resulted in tar formation. The degree of fluorination of selected halogenated groups was established and the influences of various reaction conditions (time, temperature, catalyst and concentration) were determined.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
