Arsenic removal and stabilization behavior of schwertmannite@BC (Sch@BC) in contaminated dual media (water/soil): Via sulfate exchange and chemical complexation

Abstract

Arsenic (As) is extremely harmful to the ecological environment and human health owing to its high toxicity. The composite that biochar (BC) modified by Schwertmannite (Sch), marked as Sch@BC, were prepared to remediate As-contaminated water and soil with a high efficiency. The characterization results showed that the Sch particles were successfully loaded on the BC, providing more active sites for As(V) adsorption. Compared with the pristine BC, the adsorption capacity of Sch@BC-1 was significantly improved (50.00 mg/g), of which the adsorption capacity kept stable over a wide pH range (pH = 2–8). The adsorption process conformed to pseudo-second-order kinetics and Langmuir isotherm model, which indicated that chemical adsorption was the dominant mechanism and the adsorption rate was controlled by intraparticle diffusion. Sch@BC could adsorb As(V) through electrostatic interaction and ion exchange, forming a FeAsO4 complex and removing As(V). The 5-week soil incubation experiment showed that 3% Sch@BC showed the optimal stabilization effect, while the proportion of stable crystalline Fe/Mn-bound fractionation (F4) increased. Moreover, the results of microbial community diversity showed that Sch@BC interacted with As-resistant dominant microorganisms such as Proteobacteria in soil, promoted their growth and reproduction, and improved the stability of As in soil. In summary, Sch@BC is an excellent agent with broad application prospects for remediating As-contaminated water and soil.