Abstract
Naturally arsenic (As) enriched agricultural soils represent a significant global human health risk. In this study, As fractionation and mineralogy were investigated in naturally As-enriched agricultural soils and their corresponding sand, silt and clay fractions. Median As increased generally in the order (mg/kg)∶ silt (280) < bulk (314) < sand (323)<clay (484). Sequential extraction showed that amorphous and well-crystalline Fe- and Al-oxide bound and residual As forms accounted 27-42% of total As. Well-crystalline Fe- and Al-oxide bound As was highest (40-42%) in silt and clay fractions, while residual As was generally greatest (41-55%) in bulk and sand fractions. The sand, silt and bulk soils released a consistently higher percentage of non-specifically sorbed As than the clay, but clay released more specifically-sorbed As. Arsenate (As(V)) was the dominant species in soil solutions, although arsenite (As(III)) was significant in a few samples. XRD analysis showed the presence of arsenolite (As2IIIO3) in soils and fractions. SEM/EDS observations revealed that scorodite (FeAsVO4·2H2O) and amorphous Fe-oxides were the main As-bearing minerals in soils and fractions, which were consistent with the geochemical analysis. Outcomes from this research highlight the significant environmental risks of naturally As-enriched soils.
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