Abstract

Compounds, Ph3SnCH2OAr, are available from Ph3SnCH2I and NaOAr in EtOH. The crystal and molecular structure of Ph3SnCH2OC6H4Me-p (II) has been determined by X-ray crystallography. The molecule in the crystal contains a slightly distorted tetrahedral tin atom [C-Sn-C valency angles varying from 106.9(5) to 114.1(6)°] with an intramolecular Sn---O distance of 2.900(11) A. NMR spectral data for (II) and for Ph3SnCH2OC6H3Br2-2,4 are reported.

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