Abstract
AbstractThe isomer distribution for the homogeneous sulphonation of toluene at 25.0° in 82.3 ± 0.3 wt‐% aqueous sulphuric acid has been determined by the inverse isotope dilution method as 65.1% para. 2.9% meta and 32.0% ortho. Combining these data with the relative reactivity of toluene to benzene (kt/kb) = 66.1) 1 the partial rate factors were calculated as fpMe 258; fmMe 5.7 and foMe 63.4.
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