Abstract
Nickel(II) complexes containing two and three molecules of the aromatic diamines, o-phenylenediamine, 1,8-diaminonaphthalene and 2-2′-diaminobiphenyl are described. The complexes have been characterised by magnetic and infrared and visible spectral, measurements. Those complexes containing two molecules of diamine have been shown to have D 4h symmetry. The significance of the tetragonal splitting parameter Dt and axial ligand field strengths Dq 2 of the acid groups is discussed.
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