Abstract

The crystal structure of the title compound (systematic name: β-d-gluco­pyran­osyl 2α,3β,19α,23-tetra­hydroxy­olean-12-en-28-oate chloro­methane 0.25-solvate monohydrate), C36H58O11·0.25CH3Cl·H2O, contains a triterpenyl moiety esterified with a gluco­pyran­osyl unit, a disordered mol­ecule of chloro­methane solvent with a partial site occupancy located about a twofold axis and a water mol­ecule of hydration. Three rings of the triterpenyl moiety adopt classical chair conformations, while one ring exhibits an envelope conformation and one has a flattened chair conformation. The gluco­pyran­osyl ring also adopts a chair conformation. The structure is stabilized by extensive intermolecular hydrogen bonds as well as an intramolecular interaction.

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