Abstract

A silver filling: The π-acidic, trinuclear silver(I) pyrazolate [{[3,5-(CF3)2pz]Ag}3] readily reacts with simple electron-rich aromatic hydrocarbon compounds to form sandwich complexes. The type of complex formed depends on the solvent and the arene, and includes supramolecular stacks. Additionally, some of these complexes appear to have interesting luminescence properties. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z604585_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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