Abstract

The OUSL Journal is a peer-reviewed open access journal published by the Open University of Sri Lanka (OUSL). It is the first scholarly journal in Sri Lanka focusing on research in the field of Open and Distance Learning (ODL), and is being published since 1997. The journal provides a platform to publish research and pedagogy relating to teaching and learning at the University level, and in particular to Open and Distance Learning (ODL). It also provides a forum for research and review articles related in the areas of Agriculture, Natural Sciences, Education, Engineering, Humanities and Social Sciences and Health Sciences.

Highlights

  • There has been a considerable interest in the use of P-N ligands to generate new coordination and organometallic chemistry

  • Nitrogen donors do not prefer to coordinate to metal centres with low oxidation states

  • This paper describes the syntheses of (p-cymene)Ru(II)- complexes of the phosphino dimethylhydrazone Z-PPh2CH2C(But)=NNMe2 I and the phosphino hydrazone Z-PPh2CH2C(But)=NNH2 II

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Summary

Introduction

There has been a considerable interest in the use of P-N ligands to generate new coordination and organometallic chemistry. The coordination chemistry of phosphino hydrazones (e.g. Z-PPh2CH2C(But)=NNR1R2) with Group 6, 8, 9 and 10 metal centres have been reported (Hii et al, 1992, Hii et al, 1994, Ike et al, 1998, Perera & Shaw, 1995).

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