Arc erosion behaviors of the densified Ag-SnO2 contact materials containing sub-micron and nano In2O3 additives

Abstract

The effects of In2O3 additive size on the physical properties and arc erosion behaviors of the densified Ag-SnO2 materials were investigated. Arc resistance mechanism was analyzed based on the microscopic morphology characterization. Results revealed that the physical properties of the Ag-SnO2(In2O3) materials were significantly improved after densification. Relative density and electrical conductivity of the materials reached above 99.5% and 71%IACS, respectively. The densified Ag-SnO2 material containing sub-micron In2O3 showed the low and stable break arc energy. The mass loss of the cathode was dramatically decreased by 65.4%. Importantly, the generation of pores and micro-cracks on the surface of electrodes were significantly restrained and the contact resistance became more stable. By comparison, the nano In2O3 additive less than 100 nm effectively suppressed not only the splash of molten Ag on the surface of cathode but also the aggregation of SnO2 particles on anode. The arc erosion products were obviously decreased, resulting in an enhancement of arc-erosion resistance of Ag-SnO2(nano In2O3) materials. Compared with that without additive, the mass loss of the Ag-SnO2 material which contains nano In2O3 obviously decreased from 2.3 to 1.4 mg. The optimal mass fraction of nano In2O3 in the Ag-SnO2 contact materials was 1 wt%.