Abstract
Par excitation sous champ de coordinat des complexes [Rh(tn) 2 (H 2 O) 2 ] 3+ formation d'un etat stationnaire avec isomerisations cis-trans et trans-cis de rendements quantiques: 0,29±0,05 et 0,10±0,05. Le complexe trans-[Rh(tn) 2 (H 2 O) (OH)] 2+ olisomerise en cis avec un rendement quantique ∼1. Les complexes [Rh(tn) 2 (OH) 2 ] + sont photoinertes
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