Abstract

Two-dimensional (2D) arrays of obelisk-like zinc oxide nanorods were successfully synthesized with high efficiency on quartz and glass substrate on a large scale through a simple aqueous solution deposition method with zinc nitrate, ammonia, and ammonium chloride as the precursors. Characterized by XRD, EDS, TEM and SEM, the as-grown zinc oxide rods had a single crystalline obelisk-like hexagonal wurtzite structure with diameters of about 300–400 nm and length up to 5 μm. Both XRD and SEM studies revealed the orientation of ZnO rods, and the orientation of ZnO rods can be controlled easily by temperature, pH of the reaction system and the concentration of reactants.

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