Abstract

Abstract. In this study, we describe the design and testing of a high-output-stability, constant-liquid-feed nebulizer using the Venturi principle to generate liquid particles from solutions. This atomizer, the PRinted drOpleT Generator (PROTeGE), was manufactured using stereolithography (SLA) printing. Different concentrations of ammonium sulfate solutions were used to characterize the size and number concentration of the generated particles. A comparison of a 3D printed 0.5 mm orifice against a commercially available 0.5 mm brass orifice using the same ammonium sulfate solution was also performed. The particle number concentration generated with the printed orifice was higher, by ∼×2, than the particle number concentration generated with the brass orifice. PROTeGE is also capable of dispersing polystyrene latex (PSL) spheres for calibration purposes. The particle number concentrations obtained in this study ranged from ∼ 10 000 cm−3 for 0.75 µm to ∼ 100 cm−3 for 5.0 µm PSL particles with a dependence on the concentration of the dispersed solution. For the different concentrated ammonium sulfate solutions particle number concentrations from ∼ 14 000 cm−3 for 0.1 g L−1 to 7600 cm−3 for 5.0 g L−1 were measured. An additional measurement with a scanning electrical mobility system (SEMS) was performed for the 0.6 g L−1 solution to measure particles in the size range of 10 to 1000 nm. The generated particle number size distributions (PNSDs) showed a maximum at 50 nm with particle number concentrations of ∼ 40 000 cm−3. PROTeGE is easy to manufacture and operate, low in maintenance, and cost-effective for laboratory and field generation of particles from aqueous media in a size range of 10 to 5000 nm.

Highlights

  • Reliable and cost-effective particle generation methods are necessary for applications where a well-defined mono- or polydisperse particle concentration and size are required

  • PROTeGE was immersed in a jar with destilled de-ionized (DDI) 18.2 M q cm Millipore water and sonicated for 10 min in an ultrasonic bath to ensure clean inner surfaces

  • Overall the generated particle number size distributions (PNSDs) were stable over their measured period of time while only the 1.5 μm polystyrene latex (PSL) sample showed a slight decrease

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Summary

Introduction

Reliable and cost-effective particle generation methods are necessary for applications where a well-defined mono- or polydisperse particle concentration and size are required. Similar concentrations and size ranges of aerosol particles can be produced from bulk solutions using a variety of instruments such as vibrating-orifice aerosol generators and ultrasonic nebulizers. Another common technique used to generate liquid aerosol particles is by pressurized-air nebulization. In this method, compressed air is utilized to shatter a solution into small aerosol droplets with a specific size distribution (Swiderska-Kowalczyk et al, 1997). Kong et al (2018) created aqueous aerosol particles used to study deliquescence and ice nucleation in sea salt particles.

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