Abstract
We prepared amphiphilic dendritic N-heterocyclic carbene (NHC)–gold(I) complexes having poly(ethylene glycol) units at the peripheral layer. By employing 1mol% of the dendritic NHC–gold(I) catalyst, the aqueous media carboxylative cyclization of propargylic amines proceeded smoothly to provide the corresponding 2-oxazolidinone under atmospheric pressure of CO2 at room temperature.
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