Aqueous Leaching on High Sulfur Sub-bituminous Coals, in Assam, India

Abstract

Aqueous leaching of high sulfur sub-bituminous coals from Ledo and Baragolai collieries of Makum coal fields, in Assam, India, has been investigated with respect to time at different temperatures. Leaching at 25 °C up to 120 h showed that the physicochemical characteristics viz., conductivity, acidity, TDS, and SO4-2 ions, increase with the increase in time of leaching. The generation of highly acidic leachates at 1−1.5 h (pH 2.5) and 2 h (pH 3.1) for Ledo and Baragolai coals was observed, respectively. However, it remains stable up to 120 h. The concentration of major, minor, and trace elements and their mobility along with the loss of pyritic sulfur or depyritization were also reported. The release of metals (Fe, Mg, Bi, Al, V, Cu, Cd, Ni, Pb, and Mn) above the regulatory levels during leaching was evidenced. Depyritization was found to be 79.8, 82.9, 84.7, and 89.7% for Ledo and 70.49, 73.77, 75.41, and 77.05% for Baragolai coal at 15, 25, 35, and 45 °C, respectively. A pseudo-first-order kinetic relationship with activation energies (E) of 8.1477 and 5.2378 kJ mol-1 with frequency factors (A) of 8.8405 × 10-4 and 2.6494 × 10-4 dm3 mol-1 s-1 was attributed to aqueous oxidation of pyrites in Ledo and Baragolai coals, respectively. The X-ray diffraction analysis and Fourier transform infrared spectroscopy patterns indicate the presence of illite, α-quartz, hematite, chlorite, rutile, calcite, and albite as mineral phases. This investigation justifies the formation of acid mine drainage by weathering of pyrites from coal during the mining of high sulfur Makum coal fields, in Assam, India, and demonstrates one of the possible routes for its formation.