Abstract
The aquathermolysis reactivity of nine organic sulfur compounds was investigated to determine their potential to generate hydrogen sulfide during the cyclic steam stimulation process to recover Cold Lake bitumen. Dioctyl sulfide, 1-decanethiol, didecyl disulfide, 1-naphthalenethiol, 1,1'-dinaphthyl sulfide, 1,1'-dinaphthyl disulfide, 1-naphthyl 1-octyl sulfide, tetrahydrothiophene, and thiophene were selected as model compounds and subjected to neutral, basic, and acidic aquath-ermolysis conditions at 250 and 300 o C. Thiols, and thiols formed by cleavage of sulfides and disulfides were found to be the source of H 2 S evolution. Aliphatic sulfides, in addition to their usual C-S bond cleavage, showed α,β C-C bond cleavage
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.