Abstract
The Co ion in the title compound, [CoCl(phen)2(H2O)]Cl·DMF [phen = 1,10-phenanthroline (C12H8N2) and DMF is dimethylformamide (C3H7NO)], exists in a distorted octahedral coordination environment. The cations and anions are linked by O—H⋯Cl hydrogen-bond interactions across a center of inversion, forming a dimeric entity. A supramolecular network structure is consolidated by π–π stacking interactions and hydrogen bonds.
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