Abstract
The crystal structure of the title compound, [MnCl(C 10 H 8 N 2 ) 2 (H 2 O)]ClO 4 , contains monomeric[Mn(bpy) 2 Cl(H 2 O)] + cations in which the Mn II ion is surrounded by a pair of chelating bpy ligands (bpy=2,2'-bipyridine) [Mn-N 2.235 (3)-2.291 (3) A], an aqua ligand [Mn-O 2.167 (3) A] and a chloro ligand [Mn-Cl 2.447 (1) A] in a distorted octahedral environment. Adjacent cations are linked into dimers by pairs of Cl...O hydrogen bonds [Cl...O 3.137 (3) A]
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